The full-back was added to the squad on Sunday, replacing Waldemar Anton, who withdrew from international duty due to muscular problems.
Baku will now provide Klopp with another option at full-back as Germany prepare for two important fixtures to conclude their Nations League group campaign.
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The 28-year-old RB Leipzig defender will be hoping to make an impression during the upcoming international window as Germany look to finish their group campaign strongly.
Germany face Serbia away from home on November 13 before welcoming the Netherlands to Berlin on November 16.
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